Theoretical study of highly vibrational states of nonlinear triatomic molecules using Lie algebraic approach

发布时间:2023-03-20 00:03:13

ThevibrationalexcitationsofbenttriatomicmoleculesarestudiedbyusingLiealgebra.TheRMSerroroffitting30spectroscopicdatais1.66cm-1forSO2.TheresultsshowthattheexpansionofamolecularalgebraicHamiltoniancanwelldescribetheexperimentaldata.AndthetotalvibrationallevelscanbecalculatedusingthisHamiltonian.Atthesametime,thepotentialenergysurfacecanalsobeobtainedwiththealgebraicHamiltonian.

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